In the classical Petri-net, the workflow has no strict restrictions and definition, the transition token (including type, quantity, flow direction) binding and arriving of the subsequent places in different ways, and the description and analysis of multi-performance cannot be handled effectively. A workflow weighting colored Petri-net modeling method was proposed by defining the workflow structure and color set of Petri net and adding the multi-performance analysis. The conception, weight vector and the structure of the method were introduced, and the process of dangerous chemicals logistics was teken as an example to put forward a method of modeling and performance measurement of the process of dangerous chemicals logistics from two dimensions including time and safety. Then the method was used for modeling, measuring and analyzing performance of the process of dangerous chemicals logistics, the total value of performance was 3.8094. At last, by screening the weakness of local performance, bottleneck of process of dangerous chemicals logistics was found out, thus proves that the method is a scientific method for multi-performance analysis of workflow.